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81.
Rhyolite eruptions in Iceland mostly take place at long-lived central volcanoes, examples of which are found associated with each of the present-day rift-zone ice caps. Subglacial eruptions at Kerlingarfjöll central volcano produced rhyolite tuyas that are notable for their exposures of early-erupted pyroclastic material. Observations from a number of these edifices are synthesised into a general model for explosive rhyolite tuya formation. Eruptions begin with violent phreatomagmatic explosions that generate massive tuff (mT), but the influence of water quickly declines, leading to the formation of massive lapilli-tuffs (mLT) containing magmatically-fragmented vesicular pumice and ash. These are deposited rapidly near the vent, probably by moist pyroclastic density currents, confined by ice but not within a meltwater lake. The explosive-effusive transition is controlled by the ascent rate and gas content of the magma. An unusual obsidian-rich massive lapilli-tuff lithofacies (omLT) is identified and interpreted as pyroclastic material that was intruded into gas-fluidised deposits at the explosive-effusive transition. The effusive phase of eruption involves the emplacement of intrusions and lava caps. Intrusions of lava into the early-erupted phreatomagmatic deposits are characterised by peperitic margins and the formation of hyaloclastite. Intrusions into stratigraphically higher levels of the pyroclastic material show more limited interaction with the host tephra and have microcrystalline cores. Large lava bodies with columnar-jointed margins cap the tuyas and have intrusive basal contacts with the tephras. The main influence of the ice is to confine the rhyolite eruptive products to immediately above the vent region. This is in contrast to subglacial basaltic tuya-forming eruptions, which are characterised by the formation of meltwater lakes, phreatomagmatic fragmentation and subaqueous deposition. The lack of meltwater storage may reduce the potential for large jökulhlaups.  相似文献   
82.
There has been considerable discussion but little experimental evidence regarding the comparability of in-situ and remote (shipboard or laboratory) incubations for the determination of sediment oxygen consumption and benthic nutrient flux rates. This paper presents the results of such a comparison, using in situ chamber and shipboard chemostatic systems, for a shallow station on the Louisiana, continental shelf during April 1992. Results indicated no methodological differences between rates of sediment oxygen consumption and nutrient flux (NH4 +, NO5 ?, NO2 ?, PO4 3?, and SiO2/Si(OH)2) that could be attributed to the removal of cores from shelf sediments. This conclusion implies that subcoring from box cores is no more destructive of sediment structure and salient environmental characteristics than chamber emplacement. Differences between the methods occurred when ambient oxygen concentrations were low (<2 ml l?1). These differences were caused by initial reaeration of bottom water in the shipboard system and reflect the sensitivity of heterotrophic metabolism, dissolution kinetics, and diffusive fluxes to low oxygen concentrations. The differences in exchange rates observed in this study reiterate the importance in maintaining ambient conditions in the experimental apparatus. The results of this study corroborate the small body of, data that addresses this issue and extends methodological similarities to include nutrient exchanges. Given the comparability of rates, use of remote chemostatic systems is more advantageous for work in shelf environments than in-situ batch methods due to increased statistical rigor, logistical convenience, and the ability to minimize changes in experimental conditions during incubations.  相似文献   
83.
We have surveyed 7 inland salt lakes and 14 coastal saltworks in the People's Republic of China (P. R. China) which are natural habitats for the brine shrimpArtemia. We report here on the location of the lakes, the mode of reproduction of theArtemia and the opportunities for achieving self sufficiency in cyst production for use in the local aquaculture industry. Because of frequent misunderstandings regarding the identification of a specific habitat, a new identification system for each population is proposed, using a numerical code which identifies the province, the habitat and the date of collection. Information of newArtemia populations is included as well as data on their reproduction mode.International interdisciplinary study onArtemia populations coordinated by the Laboratory of Aquaculture &Artemia Reference Center, University of Ghent, Belgium.  相似文献   
84.
Eighteen samples of the McMurdo volcanics on Ross Island, Antarctica consisting of basanitoid, trachybasalt and phonolite have been analyzed for rare earth elements (REE) in order to determine the details of differentiation using quantitative trace element modeling. The basanitoids have REE patterns similar to those for alkali basalts or nephelinites from ocean islands. Since there is no correlation between REE and silica contents among five basanitoids, some of the variability in the REE contents must be related to the extent of partial melting, variation in the residual mineralogies of the mantle during melting, or to inhomogeneities in the REE composition of the mantle.In order to explain the data, more than one differentiation sequence is necessary. In each case a basanitoid melt is the parent which differentiates to trachybasalt upon separation of olivine, clinopyroxene, spinel, ±kaersutite±plagioclase±apatite. If clinopyroxene, kaersutite, anorthoclase, plagioclase and apatite separate from a trachybasalt melt, a mafic phonolite results.If, however, no kaersutite is involved, an anorthoclase phonolite results. A distinct type of mafic phonolite results if kaersutite is one of the minerals that separates from the anorthoclase phonolite. If the anorthoclase phonolite precipitates plagioclase and anorthoclase and if the melt reacts with plagioclase-rich continental rocks, a trachyte results.Formerly spelled: Shine Soon Sun  相似文献   
85.
Bicyclanes previously reported only in heavily biodegraded Texas Gulf Coast crudes have been found to be ubiquitous in Australian crude oils of non-marine origin from four different basins. The compounds are present in oils, thought to be derived from the same or similar sources, that have undergone varying degrees of biodegradation. They are also found to be present in oils of different geological age. In addition a series of tricyclic diterpenoid hydrocarbons was common to four oils from the Gippsland Basin. Four of these compounds had the molecular formula C20H34 and mass spectral fragmentation patterns suggested they were mono-unsaturated diterpenoids. The presence of unsaturated diterpenoids in crude oils appears to be a unique observation. It is proposed that the diterpenoids may be the source of the bicyclanes also observed in these oils.  相似文献   
86.
The development and characteristics of coastal internal boundary layers were investigated in 28 tests. These were made at all seasons and in both gradient and sea-breeze flows but only during mid-day periods. Measurements of turbulence and temperature were taken from a light aircraft which flew traverses across Long Island at successive altitudes parallel to the wind direction. These were used to locate the boundary between modified and unmodified air as a function of height and distance from the coast. The same measurements plus tower measurements of wind, turbulence and temperature, pilot balloon soundings and measurements of land and water surface temperatures by a remote sensing IR thermometer were used to quantify the characteristics of the modified and unmodified air. The boundary layer slope was steep close to the land-water interface and became shallower with downwind distance. Growth of the boundary layer was initially slower with stable lapse rates upwind than with neutral or unstable conditions over the water. An equilibrium height was found in many tests except under conditions of free convection when the internal boundary layer merged into the mixed layer inland and with sea-breeze conditions. The equilibrium height depended on downwind conditions and was greater with low wind speeds and strong land surface heating than with stronger winds and small land-water temperature differences. Current theoretical models are not adequate to predict the height of the boundary layer at the altitudes and distances studied but reasonably good predictions were given by an empirical model developed earlier. Wind speed in the modified air averaged about 70% of that at the coast but turbulence levels were several times higher both near the surface and aloft. These findings have important implications for diffusion from coastal sites.  相似文献   
87.
A causeway which had restricted tidal flow in a portion of the Sheepscot River estuary was removed late in 1974. Flowmeter data from moored plankton nets fished over full tidal cycles, and salinity observations made in conjunction with the net sets, were used to evaluate the effects of causeway removal on circulation in the estuary. Tidal flows in the main channel increased by almost 50%. This increase was accompanied by substantial decreases in salinity stratification and in the strength of the gravitational circulation.  相似文献   
88.
The varve record from High Arctic, proglacial Bear Lake reveals a regionally coherent hydroclimatic signal as well as complexities due to changing hydroclimatic and limnologic conditions. Varve formation is strongly dependent on underflows that exhibit variability in strength during the past 750 yr. Periods with reduced underflow sedimentation and accumulation rates fail to produce varves in the distal part of the lake. Isolated coarse silt and sand grains occur in 80% of the varves and are interpreted to be niveo-aeolian in origin. Coarse (>500 μm) sand grains deposited on the lake ice by strong winter winds are notably less common since A.D. 1850, likely due to reduced storminess. Regression of the varve thickness record with meteorological records indicates high correlations with autumn (September and October) temperatures and total monthly snowfall. These correlations are best at times when underflow activity is sufficiently strong to produce varves throughout the lake. The close association with warmer temperatures and snow-bearing synoptic systems moving north in Baffin Bay suggests that the primary climate signal in the varves is varying autumn snow pack that controls nival discharge in the following year. The similarity between the other records of melt season temperature and sea-ice cover and the Bear Lake record suggests that summer and autumn conditions were generally similar across the Baffin Bay region through much of the last millennium.  相似文献   
89.
AOX‐formation by the Sonochemical Treatment of Salicylic Acid in Presence of Chloride Ultrasound shows great potential for improving water, wastewater and sludge treatment processes. However, a number of questions exist: for example the influence of suspended solids or salts. In this paper the influence of chloride in view of AOX‐formation should be investigated. As organic model compound salicylic acid (0.05…1 mmol/L) was used. Formation of AOX (adsorbable organically bound halogens) was measured in dependence upon chloride concentrations (1.4…141 mmol/L) and pH 2 and 9. Ultrasound irradiation was performed in glass reactor (500 mL) at 206 kHz and 353 kHz by continuous bubbling argon:oxgen (4:1) at a flow rate of 1 L/min into the solutions. The elimination of salicylic acid and the formation of hydrogen peroxide were not influenced by the presence of chloride (up to 56 mmol/L). The rate of salicylic acid elimination and the formation rate of hydrogen peroxide are at concentrations of mmol/(L min) levels but those of AOX formation of μmol/(L min) levels. The reactions leading to chlorinated by‐products can be seen as minor reaction paths. The yield of AOX depending on frequency, pH and chloride concentration lies between 10 μg/L and 900 μg/L. In acidic medium they were twice as high as in basic medium. Below the ratio chloride : salicylic acid of 2 mol/mol, AOX could not be identified.  相似文献   
90.
We calculate the chemical depletion fraction of the granitic bedrock by analysing the rock-soil enrichment of zirconium. In Vendée (France), chemical weathering rates account for 26% of the denudation rates. Such a chemical depletion fraction characterizes temperate regimes. It is three times lower than that of humid tropical regimes. To cite this article: J.-C. Maurin et al., C. R. Geoscience 337 (2005).  相似文献   
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